Other molecules with similar atomic structures that "look like" water but are not polar have very different characteristics. Here are some examples:
Hydrogen sulfide
Hydrogen sulfide (or hydrogen sulphide) is the chemical compound with the formula H2S. This colorless, toxic and flammable gas is partially responsible for the foul odor of rotten eggs and flatulence.
freezing: -85.6 degrees C
Boiling: -60.3 C
Hydrogen selanide
Hydrogen selenide is H2Se, the simplest hydride of selenium. H2Se is a colorless, flammable gas under standard conditions. It is the most toxic selenium compound with an exposure limit: 0.05 ppm over an 8 hour period. This compound has a very irritating smell of decayed horseradish.
freezing: -66 degrees C
Boiling: -42 C
Hydrogen Telluride
Hydrogen telluride is the inorganic compound with the formula H2Te. The simplest hydride of tellurium, it is rarely encountered because of its tendency to decompose to the constituent elements. Most compounds with Te-H bonds are unstable with respect to loss of H2. H2Te is chemically and structurally similar to hydrogen selenide, both are acidic species with H-X-H angles approaching 90°.
freezing: -49 degrees C
Boiling: -2 C
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